Nws siv zog npaum li cas los rhuav tshem ib daim ntawv cog lus?
Nws siv zog npaum li cas los rhuav tshem ib daim ntawv cog lus?

Video: Nws siv zog npaum li cas los rhuav tshem ib daim ntawv cog lus?

Video: Nws siv zog npaum li cas los rhuav tshem ib daim ntawv cog lus?
Video: Tsis tau koj ces mus ua hauj sam FULL INSTRUMENTAL 2024, Kaum ib hlis
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Raws li piv txwv ntawm daim ntawv cog lus dissociation enthalpy, rau tawg nce 1 mole ntawm gaseous hydrogen chloride molecules rau cais gaseous hydrogen thiab chlorine atoms yuav siv sij hawm 432 kJ. Cov daim ntawv cog lus dissociation enthalpy rau H-Cl daim ntawv cog lus yog +432 kJ mol-1.

daim ntawv cog lus enthalpy (kJ mol-1)
C-Cl +346
H-Cl +432

Tom qab ntawd, ib tug kuj yuav nug, ua li cas koj xam lub zog uas yuav tsum tau los rhuav ib daim ntawv cog lus?

Bond zog yog txhais los ntawm cov sum ntawm tag nrho cov daim ntawv cog lus tawg rho tawm tag nrho cov daim ntawv cog lus ua: ΔH = ∑H( daim ntawv cog lus tawg) - ∑ H( daim ntawv cog lus tsim). ΔH yog qhov hloov pauv hauv bond zog , kuj hu ua tus daim ntawv cog lus enthalpy thiab ∑H yog cov lej ntawm cov daim ntawv cog lus lub zog rau txhua sab ntawm lub kev sib npaug.

Ib tug kuj yuav nug, vim li cas nws thiaj li xav tau lub zog los rhuav tshem daim ntawv cog lus? Zog yog xav tau rau tawg daim ntawv cog lus . Atoms zoo siab dua thaum lawv "sib yuav" thiab tso tawm zog vim tias nws yooj yim dua thiab ruaj khov dua kom muaj kev sib raug zoo (piv txwv li, los tsim octet hluav taws xob teeb tsa). Qhov hloov pauv enthalpy yog qhov tsis zoo vim tias lub kaw lus tso tawm zog thaum tsim daim ntawv cog lus.

Tsis tas li ntawd, yuav tsum muaj zog npaum li cas los rhuav tshem cov ntawv cog lus hydrogen?

Hauv dej hydrogen bonds , cov hydrogen atom yog covalently txuas rau cov pa oxygen ntawm cov dej molecule (492.2145 kJ ˣ mol-1 [350]) tab sis muaj (zoo) qhov kev nyiam ntxiv (kwv yees 23.3 kJ mol-1 [168]. Qhov no yog qhov zog (ΔH) xav tau kev tawg tus daim ntawv cog lus thiab tag nrho cais cov atoms.

Puas rhuav ib daim ntawv cog lus tso tawm lub zog?

tawg thiab ua bonds Zog yog absorbed rau tawg daim ntawv cog lus . Bond - tawg yog ib qho txheej txheem endothermic. Zog yog tso tawm thaum tshiab daim ntawv cog lus daim ntawv. Seb cov tshuaj tiv thaiv endothermic los yog exothermic nyob ntawm qhov sib txawv ntawm qhov zog xav tau tawg daim ntawv cog lus thiab cov zog tso tawm thaum tshiab daim ntawv cog lus daim ntawv.

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