Dab tsi yog soft thiab hard acids?
Dab tsi yog soft thiab hard acids?

Video: Dab tsi yog soft thiab hard acids?

Video: Dab tsi yog soft thiab hard acids?
Video: Saum neej tsis yeej hauv dab tsis tseg.9/10/2018 2024, Kaum ib hlis
Anonim

The HSAB ( Hard Soft Acid Base) txoj kev xav categorizes hom tshuaj raws li kua qaub los yog bases thiab raws li " nyuaj ”, “ mos ", los yog "borderline". Nws piav li ntawd cov kua qaub los yog hauv paus zoo li loj thiab polarizable heev, thaum nyuaj acids los yog cov hauv paus me me thiab tsis yog polarizable.

Ib yam li ntawd ib tug yuav nug, dab tsi yog qhov nyuaj thiab mos acid thiab puag?

Lewis hauv paus tuaj yeem muab faib ua ob pawg: nyuaj bases muaj me me, kuj tsis muaj polarizable pub atoms (xws li N, O, thiab F), thiab. mos bases muaj cov loj, kuj polarizable pub atoms (xws li P, S, thiab Cl).

Ib yam li ntawd, hard acids thiab bases muab piv txwv li cas? Hlau-ligand kev sib tshuam yog ib eg a Lewis kua qaub – puag kev sib tham. Lewis hauv paus tuaj yeem muab faib ua ob pawg: nyuaj bases muaj me me, kuj tsis muaj polarizable pub atoms (xws li N, O, thiab F), thiab.

Nyuaj thiab Mos Acids thiab Bases.

Cov kua qaub Bases
nyuaj Al3+, Sc3+, Cr3+ CO32
Ti4+ PO43
mos BF3, Al2Cl6, CO2,SO3
Cu+, Ag+, Aw+, Tl+, Hg22+ H

Ib yam li ntawd, koj tuaj yeem nug, dab tsi yog ib qho kua qaub?

Cov kua qaub thiab Bases. Cov kua qaub muaj cov cations loj loj uas tsis muaj nqi thiab cov molecules nrog lub zog muaj zog nyob hauv molecular orbitals. Cov kua qaub tau yooj yim polarizable. Mos bases teb tau yooj yim dua thiab tsim cov tebchaw ruaj khov thiab cov complexes nrog cov kua qaub.

Puas yog tooj liab yog ib qho nyuaj lossis soft acid?

Nyob rau hauv no milieu, lub hauv paus ntsiab lus ntawm nyuaj thiab cov kua qaub thiab cov hauv paus (HSAB) tau yog ib qho kev qhia zoo heev rau cov kws tshuaj inorganic. Tooj (i) tau muab faib ua ib mos cation.

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