Video: Qhov twg yog lub hauv paus nyuaj?
2024 Tus sau: Miles Stephen | [email protected]. Kawg hloov kho: 2023-12-15 23:36
Lub hauv paus nyuaj yog electronegative heev thiab tsis tshua muaj polarizability. Piv txwv ntawm Hard Bases : F-, OH-, NH3, N2H4, ROH, H2O, SO42-, PO43- Lub hauv paus nyuaj react yooj yim dua los tsim cov tebchaw ruaj khov thiab cov complexes nrog nyuaj kua qaub.
Tsis tas li cov lus nug yog, cov acids nyuaj thiab cov hauv paus ua piv txwv yog dab tsi?
Hlau-ligand kev sib tshuam yog ib eg a Lewis kua qaub – puag kev sib tham. Lewis hauv paus tuaj yeem muab faib ua ob pawg: nyuaj bases muaj me me, kuj tsis muaj polarizable pub atoms (xws li N, O, thiab F), thiab.
Nyuaj thiab Mos Acids thiab Bases.
Cov kua qaub | Bases | |
---|---|---|
nyuaj | Al3+, Sc3+, Cr3+ | CO32− |
Ti4+ | PO43− | |
mos | BF3, Al2Cl6, CO2,SO3 | |
Cu+, Ag+, Aw+, Tl+, Hg22+ | H− |
Tsis tas li ntawd, vim li cas nyuaj acids nyiam cov hauv paus tawv? Txoj kev xav elaborates qhov ntawd nyuaj acids nyiam mus khi nrog nyuaj bases , thiab qhov tshwm sim adduct zoo li muaj ntau tus cwj pwm ionic hauv nws txoj kev sib txuas. Sib piv, mos acids nyiam mus khi nrog mos hauv paus , thiab lawv cov adducts yog ntau covalent nyob rau hauv qhov.
Ib sab saum toj no, puas yog oxygen lub hauv paus tawv lossis mos?
Qhov kev soj ntsuam no thaum kawg tau coj mus rau qhov kev faib tawm hu ua Hard and Soft Acids and Bases (HSAB). Hauv cov ntsiab lus, me me los yog ntau dua cov hlau ions raug hu ua hard acids. Lawv feem ntau yuav khi rau cov hauv paus tawv, uas feem ntau muaj me me pub atoms xws li oxygen lossis nitrogen.
Puas yog tooj liab yog ib qho nyuaj lossis soft acid?
Nyob rau hauv no milieu, lub hauv paus ntsiab lus ntawm nyuaj thiab cov kua qaub thiab cov hauv paus (HSAB) tau yog ib qho kev qhia zoo heev rau cov kws tshuaj inorganic. Tooj (i) tau muab faib ua ib mos cation.
Pom zoo:
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