Lub hom phiaj ntawm Diels Alder tshuaj tiv thaiv lab yog dab tsi?
Lub hom phiaj ntawm Diels Alder tshuaj tiv thaiv lab yog dab tsi?

Video: Lub hom phiaj ntawm Diels Alder tshuaj tiv thaiv lab yog dab tsi?

Video: Lub hom phiaj ntawm Diels Alder tshuaj tiv thaiv lab yog dab tsi?
Video: Lis Yaj Pov : Lub Hom Phiaj 2024, Kaum ib hlis
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Cov lub hom phiaj ntawm no lab yog los qhia txog lub tswv yim ntawm lub melting point ntawm ib qho organic compound ua thawj kauj ruam hauv kev txheeb xyuas tshuaj lom neeg ntawm qhov sib xyaw thiab tshuaj xyuas nws cov purity. Tsis tas li ntawd, koj yuav ua kom lub voj voog sib txuas los ntawm kev ua haujlwm nto moo Diels - Alder Reaction.

Tsuas yog li ntawd, lub hom phiaj ntawm Diels Alder cov tshuaj tiv thaiv yog dab tsi?

Cov Diels - Alder tshuaj tiv thaiv yog cycloaddition ntawm 4 pi + 2 pi (diene + dienophile) system uas tsim cov khoom ruaj khov dua vim qhov tseeb tias sigma daim ntawv cog lus tsim muaj kev ruaj khov dua li cov pi bonds puas lawm.

Tom qab, lo lus nug yog, vim li cas txiv neej anhydride yog Dienophile zoo? Maleic anhydride kuj yog ib tug heev zoo dienophile , vim tias cov nyhuv electron rho tawm ntawm pawg carbonyl ua rau ob lub alkene carbons ua electron-tsis zoo, thiab yog li ib qho zoo lub hom phiaj rau kev tawm tsam los ntawm pi electrons hauv diene.

Ua raws li qhov no hauv kev txiav txim siab, vim li cas anthracene ua rau Diels Alder cov tshuaj tiv thaiv?

Anthracene raug mob a Diels - Alder tshuaj tiv thaiv nrog rau cov txiv neej anhydride muab lub cycloadduct nrog cov mis C18H12O3. Cov Diels - Alder tshuaj tiv thaiv yog lub conjugate ntxiv ntawm alkene rau ib tug diene. Cov alkene uas ntxiv rau diene yog hu ua dienophile.

Dienophile txhais li cas?

dienophile (plural dinophiles ) (organic chemistry) Ib tug compound uas nkag tau nrog ib tug diene; tshwj xeeb tshaj yog ib qho alkene hauv Diels-Alder cov tshuaj tiv thaiv.

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