Cov txheej txheem:

Dab tsi yog radical stability?
Dab tsi yog radical stability?

Video: Dab tsi yog radical stability?

Video: Dab tsi yog radical stability?
Video: Mus ua nyab rau yim hmoob tsis zoo 7/27/2017 2024, Kaum ib hlis
Anonim

Radical stability hais txog lub zog theem ntawm lub radical . Yog hais tias lub internal zog ntawm lub radical yog siab, radical tsis ruaj khov. Nws yuav sim mus txog qib qis zog. Yog hais tias lub internal zog ntawm lub radical yog low, radical yog ruaj khov . Nws yuav tsis tshua muaj siab xav ua ntxiv.

Tsis tas li ntawd, koj ua li cas rau cov radicals nyob rau hauv kev txiav txim ntawm stability?

Cia peb saib ntawm xya yam hauv qab no:

  1. Stability nce nyob rau hauv qhov kev txiav txim methyl < thawj < theem nrab < tertiary.
  2. Dawb radicals stabilized los ntawm resonance.
  3. Cov dawb radicals ruaj khov los ntawm cov atoms uas nyob ib sab nrog ib leeg.
  4. Dawb radicals nce nyob rau hauv stability thaum lub electronegativity ntawm lub atom txo.

uas yog qhov ruaj khov tshaj dawb radical thiab yog vim li cas? Lub sijhawm xeem: ib qho ntawm cov dawb radicals ruaj khov tshaj plaws paub yog triphenylmethyl radical , nrhiav tau los ntawm Moses Gomberg nyob rau hauv 1900. Thaum tsis muaj oxygen, qhov radical no nyob ruaj khov nyob rau hauv chav tsev kub.

Ib sab ntawm no, puas yog phenyl radical ruaj khov?

Cov ruaj khov ntawm radicals kuj tuaj yeem nce los ntawm cov tshuaj tsw qab tsw qab ntawm cov radical carbon atom. Lub hauv paus radical carbon atom ntawm triphenylmethyl radical , piv txwv li, nqa peb phenyl pab pawg. Yog li ntawd, lub radical yog heev resonance-stabilized.

Vim li cas triphenylmethyl radical thiaj ruaj khov?

Cov triphenylmethyl tshuaj (“ trityl ”) radical yog ntau ruaj khov , vim resonance stabilization. Qhov no yog keeb kwm tseem ceeb; tus trityl radical yog thawj cov organic dawb radical yuav tsum tau cais thiab tus yam ntxwv. Cov triphenylmethyl tshuaj (“ trityl ”) radical yog ntau ruaj khov , vim resonance stabilization.

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